The Takeover (S1E18)
Terraforming hasn't had this big a PR problem since the Genesis Project! The Enterprise crew arrives at Valera III for a science lecture, but wind up mounting an investigation into murder most foul, with the chief suspect being a brilliant scientist (whose resemblance to a Bond villain is more than skin deep). The shocking truth is revealed when Geordi and Data look down a deep hole without Riker there to show them the ropes. When the indigenous life form of Velara III gets to set trippin' with the ship, it inspires your micro-brained hosts to air out their frustrations about Internet commenters mentioning other Star Trek podcasts. It's the episode where Adam and Ben start a rap feud with another show!
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